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Can we sweep our CO2 emissions under the rug?

“Public opinion is a major obstacle to underground CO2 storage”

with Laurent Catoire, Head of Chemistry and Processes Unit at ENSTA Paris (IP Paris)
On March 8th, 2022 |
3 min reading time
Laurent Catoire
Laurent Catoire
Head of Chemistry and Processes Unit at ENSTA Paris (IP Paris)
Key takeaways
  • Every year, approximately 270 million tons of CO2 are emitted into the atmosphere: ~0,1% of which are currently captured.
  • The storage of CO2 emissions underground is done through various physical or chemical capture mechanisms in specific geological environments.
  • Existing operations show that there is no major technological obstacle for the geological storage of CO2.
  • The main issue would be acceptability. The possibility – however small – of CO2 leakage in the short or long-term poses a potential hazard to local populations.
  • Thus, for now, projects are focused on the storage of CO2 at sea, like the Norwegian Sea.

The cap­ture and stor­age of car­bon diox­ide is a tech­no­logy that could make it pos­sible to con­tin­ue using fossil fuels dur­ing much of the 21st cen­tury. It par­tic­u­larly con­cerns coal, a cent­ral resource for many coun­tries since there are still more than 2,500 thermal power plants in the world. This energy is used for the pro­duc­tion of elec­tri­city and heat (cogen­er­a­tion) for indus­tri­al and domest­ic pur­poses. Coal-fired and gas-fired thermal power plants are rel­at­ively abund­ant, afford­able, avail­able and loc­ated all over the world. As such, they strengthen the secur­ity and sta­bil­ity of energy systems.

Eco­nomy and demo­graph­ics being what they are, the energy trans­ition will take time – sev­er­al dec­ades at least. While we wait for the green hydro­gen eco­nomy, we must non­ethe­less con­tin­ue to live, all the while bat­tling against the green­house effect caused by CO2 emis­sions. As such, car­bon cap­ture and stor­age offers a solu­tion to help buy us some valu­able time. CO2 emis­sions rep­res­ent approx­im­ately 270 mil­lion tons every year but today only 0.1% of indus­tri­al emis­sions are cap­tured. Need­less to say, there is work to be done!

Storing CO2 underground

Nor­mally, under­ground stor­age of CO2 is achieved through vari­ous meth­ods of phys­ic­al or chem­ic­al cap­ture, and it requires strict geo­lo­gic­al con­di­tions. As such, only very pre­cise geo­lo­gic­al envir­on­ments can be used. In par­tic­u­lar, the geo­lo­gic­al form­a­tions must not only be cap­able of con­tain­ing the CO2 but must also pre­vent lat­er­al and/or ver­tic­al migra­tion of the gas. Any leaks could con­tam­in­ate pot­able ground­wa­ter at low depths, infilt­rate the ground, or more import­antly reach the atmosphere.

The geo­lo­gic­al form­a­tions used for CO2 stor­age are mainly oil and gas reser­voirs, as well as deep saline aquifers found in sed­i­ment­ary basins. The stor­age of gas (includ­ing CO2) in these envir­on­ments has been proven to work on a large scale. It can even be per­formed dur­ing oil extrac­tion oper­a­tions (sec­ond­ary recov­ery), nat­ur­al gas stor­age, and acid­ic gas removal.

Some of the risks asso­ci­ated with CO2 cap­ture and stor­age are sim­il­ar and com­par­able to those of any oth­er indus­tri­al activ­ity for which safety and reg­u­lat­ory pro­to­cols are already estab­lished. At the moment, there are only few oper­a­tions in the world where CO2 is injec­ted and stored in the ground (USA, Aus­tralia, Canada, China and UK). Most of the time, if not exclus­ively, it is done in the con­text of an oper­a­tion motiv­ated by drivers oth­er than cli­mate change, such as oil pro­duc­tion or reg­u­lat­ory require­ments for the use of hydro­gen sulf­ide (H2S).

A complicated start

Exist­ing oper­a­tions show that there is no major tech­no­lo­gic­al obstacle for the geo­lo­gic­al stor­age of CO2. Chal­lenges and blocks thus lie else­where. They mainly stem from the high cost of the oper­a­tion, par­tic­u­larly for diluted flows, like those from power plants and indus­tri­al com­bus­tion processes.

Spe­cif­ic risks asso­ci­ated with CO2 stor­age relate to the oper­a­tion­al phase (the injec­tion, to put it simply) and the post-oper­a­tion­al phase. The greatest con­cern is linked with the pos­sible risk of CO2 leak­age in the short or long term. Neg­at­ive effects include the glob­al cli­mate impact of the return of CO2 in the atmo­sphere, as well as the loc­al health and envir­on­ment­al risks, which must there­fore be cor­rectly assessed and managed.

The oth­er obstacle is thereby more media-driv­en. We are con­cerned that pub­lic opin­ion might reject this tech­no­logy and that it could affect the large-scale imple­ment­a­tion of CO2 geo­lo­gic­al stor­age. Indeed, who will accept such a stor­age site in their town? The risks asso­ci­ated with the trans­port­a­tion and injec­tion of car­bon diox­ide are reas­on­ably well under­stood. How­ever, there exists a small pos­sib­il­ity that the CO2 stored under­ground could leak from a reser­voir, either by an uniden­ti­fied migra­tion path­way, or because of a well defect.

The threat that it could rep­res­ent must be assessed in com­par­is­on with vol­can­ic CO2 emis­sions, which are nat­ur­al. Dif­fuse CO2 emis­sions from the soil or via car­bon­ated sources in vol­can­ic areas do not seem to rep­res­ent a threat, provided that the CO2 can dis­perse in the atmo­sphere. How­ever, CO2 is dan­ger­ous when it accu­mu­lates in closed spaces. Thus, large clouds of CO2 linked with sud­den emis­sions com­ing from vol­can­ic vents or craters are a deadly threat. The Lake Nyos dis­aster in 1986 in Cameroon, which res­ul­ted in 1,800 deaths from CO2 asphyxi­ation, serves as a reminder.

More acceptable solutions

Even if few ana­lo­gies exist between such an event and a pos­sible CO2 leak from a reser­voir, the risk is not null. This dis­aster is there­fore likely to come up in the media and will arouse hos­til­ity in pop­u­la­tions liv­ing in prox­im­ity of a poten­tial stor­age site. Murphy’s law will pre­vail over any oth­er consideration.

In this case, only one option remains viable: stor­ing CO2 in the open sea. In Europe, the Nor­we­gi­an Sea is often cited. How­ever, this does not mean that there would not be any impact in the event of a release of CO2. Leak­age of gas under the sea would res­ult in water acid­i­fic­a­tion around the stor­age site, with pos­sible dam­age for fauna and flora close by. This has been examined in eco­tox­ic­o­logy stud­ies. But in any case, this CO2 release – even in the event of a sig­ni­fic­ant leak – would not dir­ectly affect human health since it would be under the sea. This is there­fore reas­sur­ing for the pub­lic. Social accept­ance of this altern­at­ive is there­fore the only vari­able cap­able of accel­er­at­ing the imple­ment­a­tion of tech­no­lo­gies for redu­cing anthro­po­gen­ic CO2 emis­sions in the atmosphere.

Contributors

Laurent Catoire

Laurent Catoire

Head of Chemistry and Processes Unit at ENSTA Paris (IP Paris)

Laurent Catoire is a professor in applied chemical kinetics, in particular in combustion and in general in all reactive systems. After a DGA thesis, he has been working for 30 years on reactive systems that are little studied, poorly known but with important or potentially important applications (hypergolic systems in space propulsion, civil and military energetic materials (explosives, propellants and gas generators), energetic ionic liquids, nanothermites, aluminium combustion, metal combustion, etc).

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