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Batteries: the challenges of energy storage multiply

Quantum batteries: rethinking energy storage is possible

with James Quach, Chief Scientist at the Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia
On April 19th, 2023 |
3 min reading time
QUATCH_James
James Quach
Chief Scientist at the Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia
Key takeaways
  • Quantum batteries have the potential to accelerate charging time and even harvest energy from light.
  • Unlike electrochemical batteries that store ions and electrons, a quantum battery stores the energy from photons.
  • Quantum batteries charge faster as their size increases thanks to quantum effects such as entanglement and superabsorption.
  • They will not be able to power electric vehicles but could improve the efficiency of solar cells and be used for small electronic devices.
  • Ultimately, the challenge is to evolve these batteries, as these devices could serve as true small off-grid power sources.

A bat­tery is a device that stores energy: a quantum bat­tery is no excep­tion. In the­ory, it is a quantum mech­an­ic­al sys­tem that stores the energy of photons rather than elec­trons and ions, as is the case with con­ven­tion­al elec­tro­chem­ic­al bat­ter­ies. Unlike nor­mal bat­ter­ies, quantum bat­ter­ies charge faster as their size increases thanks to quantum effects such as entan­gle­ment and super­ab­sorp­tion – a prop­erty that could prove use­ful in mak­ing more effi­cient light – har­vest­ing devices, such as sol­ar cells.

Sev­er­al research teams around the world are work­ing on the quantum bat­tery concept, which was first form­ally pro­posed just 10 years ago by Robert Alicki of the Uni­ver­sity of Gdańsk in Poland and Mark Fannes of KU Leuven in Bel­gi­um. These devices take advant­age of quantum particles which, unlike clas­sic­al particles that have defined prop­er­ties, can sim­ul­tan­eously be in a super­pos­i­tion of sev­er­al states. Quantum particles can also influ­ence oth­er isol­ated particles, with the state of one instantly influ­en­cing the state of the oth­ers – regard­less of the dis­tance between them. This phe­nomen­on, known as entan­gle­ment, allows a quantum bat­tery to recharge more quickly, as the great­er the num­ber of entangled particles, the faster they col­lect­ively move from a low-energy state to a high-energy state1.

Quantum bat­ter­ies could be exploited to improve the effi­ciency of sol­ar cells.

Last year, James Quach and col­leagues at the Uni­ver­sity of Adelaide in Aus­tralia demon­strated that this concept works even if all the quantum particles in the sys­tems could not be fully entangled. Based on a sim­pli­fied ver­sion of a mod­el cre­ated by a team at the Itali­an Insti­tute of Tech­no­logy in Gen­oa2, their bat­tery com­prises molecules of a semi­con­duct­ing organ­ic dye, known as Lumo­gen F Orange, that are all identic­al and have a low-energy and a high-energy state. When exposed to light of a cer­tain wavelength, a molecule in the low-energy state can absorb a photon and switch to the excited state.

A distributed Bragg reflector

James Quach and his col­leagues placed the molecules between two highly reflect­ive, micron-sized mir­rors in a device known as a dis­trib­uted Bragg reflect­or, which con­sists of sev­er­al altern­at­ing lay­ers of dielec­tric mater­i­al. They then loaded these molecules with laser light. To ensure that the molecules absorbed the photons effi­ciently, they sus­pen­ded them in an inert poly­mer matrix.

The research­ers observed that the rate at which the mir­ror cav­ity absorbed light – that is, the rate at which the sys­tem charged – far exceeded what would be pos­sible if each molecule absorbed light indi­vidu­ally without any entan­gle­ment3. This effect is known as super­ab­sorp­tion and occurs because all the molecules act col­lect­ively through quantum super­pos­i­tion. They also found that the char­ging time decreased as they increased the size of the microcav­ity, and there­fore the num­ber of molecules.

With a bil­lion extra molecules, a quantum bat­tery would provide enough energy to light up a light-emit­ting diode.

Like any oth­er quantum sys­tem, the bat­tery will need to be isol­ated from its envir­on­ment before it can be scaled up. This is due to a phe­nomen­on called deco­her­ence, which is the trans­ition at which a quantum sys­tem starts to behave like a clas­sic­al sys­tem. In the short to medi­um term, there­fore, it is unlikely that quantum bat­ter­ies will be able to power large objects such as elec­tric vehicles. “How­ever, they could be exploited to improve the effi­ciency of sol­ar cells by improv­ing the cap­ture of low-light energy in photo­vol­ta­ic mater­i­als,” explains James Quach. In this con­text, a small amount of deco­her­ence may actu­ally be bene­fi­cial for charge stor­age, as it would pre­vent quantum effects that rap­idly dis­charge the battery.

“How­ever, we still have a lot of work to do before we can reli­ably exploit super­ab­sorp­tion out­side the lab,” he admits. “For example, cur­rent sol­ar cells and cam­er­as can store energy from a wide range of wavelengths, where­as our quantum bat­tery can only absorb light at a spe­cif­ic wavelength. How­ever, we are con­fid­ent that we can scale the sys­tem and pro­duce devices that can be eas­ily integ­rated into exist­ing technologies.”

Many challenges remain

While, in prin­ciple, quantum bat­ter­ies could con­trib­ute to the energy trans­ition, many chal­lenges remain. One of these is find­ing a way to main­tain the right level of energy that they can store and release it in a simple and reli­able way.

Last but not least, the molecu­lar cav­ity developed by James Quach and his col­leagues only stores photons of light. To con­vert this light into usable elec­tri­city, they need to incor­por­ate a con­duct­ive lay­er into which elec­trons from charged molecules can be trans­ferred. Many more molecules will also have to be added to the sys­tem. With a bil­lion more molecules, for example, a quantum bat­tery might be able to provide enough energy to light up a light-emit­ting diode. These devices could also be used in small elec­tron­ic devices such as watches, phones, tab­lets, or laptops – in fact, any product that needs the stored energy.

In the long term, the research­ers obvi­ously want to devel­op their bat­ter­ies fur­ther. The stakes are high, because these devices could serve as small off-grid energy sources and power Inter­net of Things devices. They would be sim­il­ar to cur­rent sol­ar pan­els and bat­ter­ies, but because the char­ging and stor­age func­tions are housed in a single sys­tem, they would be easi­er to integ­rate and use.

“The aim is to pro­duce such devices with­in three to five years,” says James Quach.

Isabelle Dumé 
1https://iopscience.iop.org/article/10.1088/1367–2630/17/7/075015/meta
2https://​journ​als​.aps​.org/​p​r​l​/​a​b​s​t​r​a​c​t​/​1​0​.​1​1​0​3​/​P​h​y​s​R​e​v​L​e​t​t​.​1​2​0​.​1​17702
3https://​www​.sci​ence​.org/​d​o​i​/​p​d​f​/​1​0​.​1​1​2​6​/​s​c​i​a​d​v​.​a​b​k3160

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